H2_Qlines_Readme.txt
Transition emission probabilities from np pi- ungerade (n>2) rovibrational levels towards X of the H2 molecule.
(Compilation by M. Glass-Maujean, June 2014)
The data contain the transition energies E(cm-1) and the line emission probabilities of Q lines from the rovibrational levels (v', J')
of upper states np pi- towards the rovibrational levels (v", J") of the ground electronic state X (J'=J").
The data display values up to the J'=4 upper rotational levels.
The calculated data are obtained by performing MQDT ab-initio calculations described in the paper:
M. Glass-Maujean and Ch Jungen, J. Phys. Chem. A 113 (47), 13124 (2009).
the * symbol indicates that the transition probabilities have been summed up a giant resonance.
The experimental values of the transition energies are from the references:
G. Herzberg and Ch. Jungen, J. Mol. Spectrosc. 41, 425 (1972).
S. Takezawa, J. Mol. Spectrosc. 52, 2575 (1970).
M. Glass-Maujean, S. Klumpp, L. Werner et al., Molecular Physics 105 (11-12), 1535 (2007).
G. D. Dickenson, T. I. Ivanov, M. Roudjane et al., J. Phys. Chem. 133 (4), 144317 (2010).
M. Glass-Maujean, Ch Jungen, G. Reichardt et al., Physical Review A 82 (6), 062511 (2010).
A. Glass-Maujean, Ch Jungen, H. Schmoranzer et al., J. Mol. Spectrosc. 293-294, 19 (2013).
M. Glass-Maujean, Ch. Jungen, A. Spielfiedel et al., J. Mol. Spectrosc. 293-294, 1 (2013).
The experimental values of the transition probabilities are from the references:
M. Glass-Maujean, S. Klumpp, L. Werner et al., Molecular Physics 105 (11-12), 1535 (2007).
M. Glass-Maujean, Ch Jungen, G. Reichardt et al., Physical Review A 82 (6), 062511 (2010).
A. Glass-Maujean, Ch Jungen, H. Schmoranzer et al., J. Mol. Spectrosc. 293-294, 19 (2013).
M. Glass-Maujean, Ch. Jungen, A. Spielfiedel et al., J. Mol. Spectrosc. 293-294, 1 (2013).
Description of the table of Q lines (a total of 3914 lines)
Col 1 : Vu is for v', vibrational quantum number of the upper level
Col 2 : Ju for J', rotational quantum number of the upper level
Col 3 : Vl for v'', vibrational quantum number of the lower level
Col 4 : Jl for J'', rotational quantum number of the lower level
Col 5 : n value of the np pi- level
Col 6 : calculated value of the transition energy (wavenumber) in cm-1,
Col 7 : observed - calculated transition energy values, with the error bar within parenthesis, in cm-1
Col 8 : calculated emission probability (in 10^6 s-1)
Col 9 : experimental emission probability (in 10^6 s-1) with the error bar within parenthesis
Col 10 : experimental value of the fluorescence rate in %.
